Solid–Solid Crystal Transitions (? to ?) in Poly(hexamethylene carbonate) and Poly(octamethylene carbonate)

نویسندگان

چکیده

Poly(hexamethylene carbonate) (PC6) and poly(octamethylene (PC8) were studied under different crystallization conditions. Using differential scanning calorimetry (DSC), a new solid–solid transition, denoted ? to ? was detected at low temperatures (<RT) in both PC6 PC8 samples. The transition represented by exothermic (i.e., ?) [?6 °C ?20 (PC8)] endothermic peaks ?) [15 28 during cooling heating DSC scans, respectively. Isothermal tests revealed that this depends on the specific thermal history because it is not observed isothermal higher than room temperature. Still, subsequent scans. Wide-angle X-ray scattering (WAXS) Fourier-transform infrared (FT-IR) spectroscopy experiments performed conditions identical those which performed. WAXS showed lower d-spacings phase one, corresponding unit cell shrinkage, explained more efficient packing of methylene groups phase. also characterized, according FT-IR experiments, ordered conformation reflected appearance absorption band) compared less

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ژورنال

عنوان ژورنال: Macromolecules

سال: 2021

ISSN: ['0024-9297', '1520-5835']

DOI: https://doi.org/10.1021/acs.macromol.1c01188